Jennifer Aniston and Brad Pitt were once one of Hollywood's most beloved couples. Although they didn't start dating for a few years after they met, the duo got married in 2000 and spent five years together before calling it quits in 2005. Since that time, Aniston has stayed pretty quiet about her marriage to the actor, although the media had plenty to say about the situation. Aniston and Pitt's split took place shortly after rumors popped up that the actor had been getting close to his "Mr. and Mrs. Smith" co-star Angelina Jolie. Just months after Aniston filed for divorce, Pitt and Jolie came out as a couple in a W Magazine spread (via Glamour).